1. Introduction
Hydroxyethyl Cellulose (HEC) is a nonionic cellulose ether obtained by reacting natural cellulose with ethylene oxide after alkali treatment. HEC has been widely used in the coatings industry due to its unique physical and chemical properties, such as high water solubility, good viscosity adjustment ability and surface activity.
2. Basic characteristics of HEC
HEC has the following significant characteristics, making it an important additive in the coatings industry:
Water solubility: HEC can be completely dissolved in cold water to form a clear or microemulsion solution, which enables it to effectively adjust the viscosity of the coating.
Thickening effect: HEC has excellent thickening properties and can significantly increase the viscosity of the solution at low concentrations, thereby improving the workability and film properties of the coating.
Suspension stability: HEC can stabilize the suspension and prevent the sedimentation of pigments or fillers in the coating, thereby improving the uniformity and stability of the coating.
Thixotropy: HEC gives the coating system good thixotropy, that is, under the action of shear force, the viscosity of the coating decreases, which is convenient for construction; when the shear force is released, the coating quickly recovers its original viscosity, reducing sagging and splashing.
Protective colloid effect: HEC can form protective colloids to prevent flocculation of latex polymers and improve the stability of the coating.
3. Specific application of HEC in coatings
3.1 Latex paint
The application of HEC in latex paint is mainly reflected in thickeners, stabilizers and water retainers:
Thickener: HEC can significantly increase the viscosity of latex paint, thereby improving the fluidity and construction of the paint. By adjusting the concentration of HEC, the appropriate viscosity required for different construction methods (such as brushing, rolling, and spraying) can be obtained.
Stabilizer: HEC can effectively prevent the sedimentation of pigments and fillers in latex paints, and improve the uniformity and storage stability of the paint.
Water-retaining agent: HEC has good moisture retention. During the construction process, it can prevent the water on the paint surface from evaporating too quickly, thereby avoiding cracking and powdering of the paint film and improving the flatness and durability of the paint film.
3.2 Water-based wood paint
In water-based wood paint, HEC is mainly used as a leveling agent and sag control agent:
Leveling agent: HEC gives water-based wood paint good leveling properties, which helps to form a uniform and smooth paint film when coating the wood surface, reducing brush marks and orange peel.
Sag control: By improving the thixotropy of water-based wood paint, HEC can effectively control the sag of the paint when it is applied on a vertical surface, improving construction efficiency and paint film quality.
3.3 Architectural coatings
In architectural coatings (such as exterior wall coatings and interior wall coatings), HEC plays an important role as a thickener, dispersant and film-forming aid:
Thickener: HEC increases the viscosity of architectural coatings, making it have good construction properties during construction, reducing sag and dripping, and ensuring the thickness and uniformity of the coating.
Dispersant: HEC can disperse and stabilize pigment particles, prevent them from agglomerating and settling, and improve the dispersion and uniformity of the coating.
Film-forming aid: HEC can improve the film-forming properties of the coating, promote the formation and drying of the paint film, and improve the mechanical properties and durability of the paint film.
3.4 Special coatings
In some special coatings (such as anti-corrosion coatings, fire-retardant coatings, and thermal insulation coatings), HEC enhances the special performance requirements of the coating through its thickening, stabilization, and rheology control functions:
Anti-corrosion coatings: HEC improves the viscosity and suspension stability of anti-corrosion coatings, which helps to evenly coat and form a dense protective layer.
Fire-retardant coatings: The high viscosity and film-forming properties of HEC help fire-retardant coatings form a protective layer at high temperatures and improve the fire resistance of the coating.
Thermal insulation coatings: HEC gives thermal insulation coatings good suspension stability and workability, allowing the coating to be evenly distributed during the coating process and improving the thermal insulation effect.
4. HEC selection and use precautions
When selecting and using HEC, the following points should be noted:
Viscosity selection: Select the appropriate HEC viscosity grade according to the different coating systems. For example, high-viscosity HEC is suitable for coating systems with high solid content or high viscosity, while low-viscosity HEC is suitable for systems with low solid content or low viscosity.
Addition method: In order to avoid the formation of lumps when HEC is dissolved in water, the method of gradual addition and stirring is usually adopted, and the temperature is appropriately increased and the stirring time is extended during the dissolution process.
Compatibility: When HEC is compatible with other additives (such as dispersants and defoamers), attention should be paid to their interaction to avoid compatibility problems and affect the performance of the coating.
5. Future development trend
With the continuous development of the coating industry, the requirements for coating performance are increasing day by day. As an important functional additive, HEC has broad application prospects. In the future, the application of HEC in coatings may develop in the following directions:
Green and environmental protection: Develop low-VOC, solvent-free HEC products to meet environmental protection requirements and market demand.
Functional modification: Through chemical modification or physical modification, HEC is given new functional properties, such as antibacterial, antifouling, self-cleaning, etc.
High-performance coatings: Develop HEC products suitable for high-performance coatings to meet the special requirements of high-performance coatings in the fields of construction, automobiles, ships, etc.
Hydroxyethyl cellulose (HEC), as a multifunctional additive, plays an important role in the coatings industry. Its excellent thickening, suspension, thixotropic and protective colloid effects make HEC widely used in latex paints, water-based wood paints, architectural coatings and special coatings. With the continuous development of the coatings industry, the application prospects of HEC will be broader. In the future, by improving the environmental performance and functional characteristics of HEC, its application value in coatings will be further enhanced.
Post time: Feb-17-2025